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[reaction: see text] Representative simple or polyhydroxylated, pyrrolidine (e.g, DRAM) or piperidine (e.g., DNJ) imines not only are potential carbohydrate-processing enzyme inhibitors that may be formed as regioisomeric variants but also are scaffolds that may be rapidly elaborated to diversely functionalized aza-sugars through highly diastereoselective organometallic additions.

Original publication

DOI

10.1021/ol016970o

Type

Journal article

Journal

Org Lett

Publication Date

10/01/2002

Volume

4

Pages

103 - 106

Keywords

Aza Compounds, Carbohydrates, Cyclization, Imines, Magnetic Resonance Spectroscopy, Molecular Mimicry