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An efficient way to prepare functionalized 8-iodo-2-trifluoromethanesulfonyloxyquinolines is presented. The iodo functionality could be selectively converted into other residues via an iodine-magnesium exchange reaction. In addition, the trifluoromethanesulfonate functionality was used as a leaving group in Negishi cross-coupling reactions.

Type

Journal article

Journal

Synthesis

Publication Date

05/03/2003

Pages

233 - 242