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Functionalized magnesium reagents have been prepared via an iodine-magnesium exchange. These reagents can be either trapped directly with aldehydes or transmetallated to copper or zinc to participate in cross-coupling reactions. The iodine-magnesium exchange, represent a unique method for the preparation of aryl and heteroaryl magnesium reagents.

Type

Journal article

Journal

Synthesis

Publication Date

09/04/2002

Pages

565 - 569