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[reaction: see text] Conformationally restricted amino alcohols based on carbohydrate scaffolds provide flexible and fine-tuneable libraries that greatly expand the range of ligands available in the Zn(OTf)(2)-mediated addition of alkynes to aldehydes, in some cases with very high stereoselectivities.

Original publication

DOI

10.1021/ol052503l

Type

Journal article

Journal

Org Lett

Publication Date

19/01/2006

Volume

8

Pages

207 - 210

Keywords

Aldehydes, Alkynes, Amino Alcohols, Carbohydrates, Combinatorial Chemistry Techniques, Ligands, Mesylates, Stereoisomerism