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A highly diastereoselective cyclopropanation protocol has been employed in the syntheses of trans-SCH-A and cis-SCH-A. This strategy encompasses a stereodivergent procedure for the preparation of syn- and anti-cyclopropane diastereoisomers in high dr from a common allylic carbamate precursor.

Original publication

DOI

10.1021/ol101295t

Type

Journal article

Journal

Org Lett

Publication Date

16/07/2010

Volume

12

Pages

3152 - 3155

Keywords

Cyclopropanes, Nitriles, Piperazines, Receptors, Somatostatin, Stereoisomerism, Urea