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A stereodivergent protocol for the aziridination of a range of cyclic allylic amine derivatives has been developed. syn-Products can be obtained in >99:1 dr under H-bonded control and anti-products are obtained in >99:1 dr under steric control by judicious choice of the N-protecting groups. © 2010 Elsevier Ltd. All rights reserved.

Original publication

DOI

10.1016/j.tet.2010.06.059

Type

Journal article

Journal

Tetrahedron

Publication Date

21/08/2010

Volume

66

Pages

6806 - 6813