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Controlled site-selective glycosylation can be achieved by combining site-directed cysteine mutagenesis with chemical modification of the introduced thiol; a new class of more efficient chemoselective reagents, glycosyl phenylthiosulfonates, allow rapid glycosylations of representative simple thiols, peptides and proteins.

Original publication

DOI

10.1039/b306990g

Type

Journal article

Journal

Org Biomol Chem

Publication Date

07/11/2003

Volume

1

Pages

3642 - 3644

Keywords

Glycoproteins, Indicators and Reagents, Molecular Structure, Spectrometry, Mass, Electrospray Ionization, Thiosulfonic Acids